Statistics for Structural Effects in Solvolytic Reactions. 35. Carbon-13 Nuclear Magnetic Resonance Studies of Carbocations. Effect of Increasing Electron Demand on the Carbon-13 Nuclear Magnetic Resonance Shifts in 2-Aryl-2-butyl and 4-Aryl-4-heptyl Carbocations. Correlation of the Data by a New Set of Substituent Constants, σ < sup > C < /sup > < sup > + < /sup >
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