Synthetic applications of the Baylis-Hillman adducts: A simple stereoselective synthesis of (E)-3-(nitroxymethyl)alk-3-en-2-ones

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Date
2000-08-04
Authors
Basavaiah, Deevi
Suguna Hyma, Rachakonda
Kumaragurubaran, Nagaswamy
Journal Title
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Abstract
First simple, stereoselective synthesis of (E)-3-(nitroxymethyl)alk-3-en-2-ones from Baylis-Hillman adducts (4-hydroxy-3-methylenealkan-2-ones) is described. (C) 2000 Elsevier Science Ltd.
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Keywords
(E)-3-(nitroxymethyl)alk-3-en-2-ones, Baylis-Hillman reaction, Methyl vinyl ketone, Stereo- selectivity
Citation
Tetrahedron. v.56(32)