Synthesis, characterization, and crystal structures of [Cu(phen) < inf > 2 < /inf > Cl]Cl. 6.5H < inf > 2 < /inf > O and [Cu(phen) < inf > 2 < /inf > Br]Br

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dc.contributor.author Onawumi, O. O.
dc.contributor.author Adekunle, F. A.
dc.contributor.author Ibrahim, A. O.
dc.contributor.author Rajasekharan, M. V.
dc.contributor.author Odunola, O. A.
dc.date.accessioned 2022-03-27T09:15:40Z
dc.date.available 2022-03-27T09:15:40Z
dc.date.issued 2010-02-01
dc.description.abstract Two mixed-ligand complexes of copper(II) with 1,10-phenanthroline and halides [Cu(phen)2Cl]Cl.6.5H2O (1) and [Cu(phen) 2 Br]Br (2), have been synthesized and characterized by microanalysis, spectroscopic, magnetic and single-crystal X-ray diffraction studies. The two complexes are isostructural in which the coordination geometry about the copper(II) ion is that of a trigonal bipyramid, with the central copper atom bound to one chloride (I) and one bromide (2) atom and four nitrogen atoms of the two phenanthroline ligands. The result of IR, electronic spectra, electron spin resonance (ESR) and magnetic measurements are discussed. Copyright © Taylor & Francis Group, LLC.
dc.identifier.citation Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry. v.40(2)
dc.identifier.issn 15533174
dc.identifier.uri 10.3109/10799890903555673
dc.identifier.uri https://dspace.uohyd.ac.in/handle/1/12663
dc.subject Electron spin resonance
dc.subject Electronic spectra
dc.subject Mixed-ligands
dc.subject Synthesis
dc.subject X-ray
dc.title Synthesis, characterization, and crystal structures of [Cu(phen) < inf > 2 < /inf > Cl]Cl. 6.5H < inf > 2 < /inf > O and [Cu(phen) < inf > 2 < /inf > Br]Br
dc.type Journal. Article
dspace.entity.type
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