A Stereospecific Synthesis of Trisubstituted Alkenes via Hydridation of Dialkylhaloboranes Followed by Hydroboration-Iodination of Internal Alkynes
A Stereospecific Synthesis of Trisubstituted Alkenes via Hydridation of Dialkylhaloboranes Followed by Hydroboration-Iodination of Internal Alkynes
dc.contributor.author | Brown, Herbert C. | |
dc.contributor.author | Basavaiah, D. | |
dc.contributor.author | Kulkarni, Surendra U. | |
dc.date.accessioned | 2022-03-27T09:06:13Z | |
dc.date.available | 2022-03-27T09:06:13Z | |
dc.date.issued | 1982-01-01 | |
dc.description.abstract | Dialkylvinylboranes, prepared conveniently via the hydridation of dialkylhaloboranes in the presence of an internal alkyne, react with iodine under basic conditions to produce trisubstituted alkenes of established stereochemistry, providing a general synthesis of trisubstituted alkenes with unambiguous stereochemistry. © 1982, American Chemical Society. All rights reserved. | |
dc.identifier.citation | Journal of Organic Chemistry. v.47(1) | |
dc.identifier.issn | 00223263 | |
dc.identifier.uri | 10.1021/jo00340a045 | |
dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/jo00340a045 | |
dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/12419 | |
dc.title | A Stereospecific Synthesis of Trisubstituted Alkenes via Hydridation of Dialkylhaloboranes Followed by Hydroboration-Iodination of Internal Alkynes | |
dc.type | Journal. Letter | |
dspace.entity.type |
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