Simple syntheses of Co < inf > 2 < /inf > (CO) < inf > 8 < /inf >  and NaCo(CO) < inf > 4 < /inf >  reagents by the reduction of CoCl < inf > 2 < /inf >  (or CoBr < inf > 2 < /inf > ) under carbon monoxide at atmospheric pressure

dc.contributor.author	Devasagayaraj, A.
dc.contributor.author	Achyutha Rao, S.
dc.contributor.author	Periasamy, M.
dc.date.accessioned	2022-03-27T09:12:27Z
dc.date.available	2022-03-27T09:12:27Z
dc.date.issued	1991-02-19
dc.description.abstract	The reduction of CoCl2 by MgH2 in tetrahydrofuran in the presence of carbon monoxide gives Co2(CO)8, which on treatment with an alkyne and norbornene gives the Pauson-Khand reaction. The reduction of CoCl2 or CoBr2 by sodium naphthalenide in THF in the presence of carbon monoxide gives NaCo(CO)4, which has been used for cyclization of certain benzylic halides into the corresponding cyclic ketones. © 1991.
dc.identifier.citation	Journal of Organometallic Chemistry. v.403(3)
dc.identifier.issn	0022328X
dc.identifier.uri	10.1016/0022-328X(91)86487-B
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/0022328X9186487B
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12584
dc.title	Simple syntheses of Co < inf > 2 < /inf > (CO) < inf > 8 < /inf > and NaCo(CO) < inf > 4 < /inf > reagents by the reduction of CoCl < inf > 2 < /inf > (or CoBr < inf > 2 < /inf > ) under carbon monoxide at atmospheric pressure
dc.type	Journal. Article
dspace.entity.type

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