Studies of phosphazenes. Part 22. High-field nuclear magnetic resonance investigation of novel isomeric oxophosphazadienes
Studies of phosphazenes. Part 22. High-field nuclear magnetic resonance investigation of novel isomeric oxophosphazadienes
| dc.contributor.author | Swamy, K. C.Kumara | |
| dc.contributor.author | Krishnamurthy, Setharampattu S. | |
| dc.date.accessioned | 2022-03-27T10:00:50Z | |
| dc.date.available | 2022-03-27T10:00:50Z | |
| dc.date.issued | 1985-12-01 | |
| dc.description.abstract | The reaction of N3P3(NPPh3)Cl5 with an excess of methoxide yields the 'hydroxy'-derivatives, N3P3(NPPh3)(OMe)4(OH) and N3P3(NPPh3)(OMe)3(OH)2, in addition to the fully methoxylated derivative N3P3(NPPh3)(OMe)5. The analogous reaction of gem-N3P3(NPPh3)(NMe2)Cl4 with methoxideaffords N3P3(NPPh3)(NMe2)(OMe)4 and N3P3(NPPh3)(NMe2)(OMe) 3(OH). The 'hydroxy'- derivatives exist in their oxophosphaza-tautomeric forms. For the 'monohydroxy'-compounds, the presence of a pair of cis- and trans-oxophosphazadienes is established from 1H and 31P n.m.r. spectroscopic data. | |
| dc.identifier.citation | Journal of the Chemical Society, Dalton Transactions | |
| dc.identifier.issn | 14727773 | |
| dc.identifier.uri | 10.1039/DT9850001431 | |
| dc.identifier.uri | http://xlink.rsc.org/?DOI=dt9850001431 | |
| dc.identifier.uri | https://dspace.uohyd.ac.in/handle/1/13525 | |
| dc.title | Studies of phosphazenes. Part 22. High-field nuclear magnetic resonance investigation of novel isomeric oxophosphazadienes | |
| dc.type | Journal. Article | |
| dspace.entity.type |
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