Novel reactions of low valent titanium and zirconium reagents generated by reduction of Cp < inf > 2 < /inf > TiCl < inf > 2 < /inf >  and Cp < inf > 2 < /inf > ZrCl < inf > 2 < /inf >  with magnesium and 1,2-dibromoethane

dc.contributor.author	Achyutha Rao, S.
dc.contributor.author	Periasamy, M.
dc.date.accessioned	2022-03-27T09:12:48Z
dc.date.available	2022-03-27T09:12:48Z
dc.date.issued	1988-09-06
dc.description.abstract	The reduction of Cp2MCl2 (M = Ti or Zr) with Grignard grade magnesium and 1,2-dibromoethane in THF at 0° C gives the corresponding metallocene-ethylene complexes along with hydride species, as indicated by the reaction with diphenyl-acetylene to give 1,2-diphenyl-(E)-1-butene. The reactions of the Cp2ZrCl2/1,2-dibromobenzene/Mg system in THF with diphenylacetylene and norbornene are also described. © 1988.
dc.identifier.citation	Journal of Organometallic Chemistry. v.352(1-2)
dc.identifier.issn	0022328X
dc.identifier.uri	10.1016/0022-328X(88)83026-2
dc.identifier.uri	https://www.sciencedirect.com/science/article/abs/pii/0022328X88830262
dc.identifier.uri	https://dspace.uohyd.ac.in/handle/1/12593
dc.title	Novel reactions of low valent titanium and zirconium reagents generated by reduction of Cp < inf > 2 < /inf > TiCl < inf > 2 < /inf > and Cp < inf > 2 < /inf > ZrCl < inf > 2 < /inf > with magnesium and 1,2-dibromoethane
dc.type	Journal. Article
dspace.entity.type

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